CHEMISTRY: PERIODIC
TABLE.
Periodic Table
Mandeleev's Periodic Table
Introduction
In 1969 a Russian chemist studied the properties
of elements, on the basis of experimental results, Mendeleev put
forwarded a law which is known as periodic law. The periodic law
can be stated as
The properties of the elements are the periodic function of their
atomic masses.
If the elements are arranged in order to increase atomic masses
then similar properties reoccur with definite intervals. Mandeleev
arrange the known elements in order to increase atomic masses in
the form of table, which is known as Mandeleev's Table. In this
table, the elements with similar properties appear in the same vertical
column known as groups, the horizontal rows of the elements are
called periods.
Advantages of Mandeleev's Periodic Table
Mandeleev's periodic table had a number of advantages over the classification
developed till that time.
1. Prediction of New Elements
While arranging the elements in order to increase atomic masses
in the table, Mandeleev come across certain positions where no known
element was seen fit to him. He left those spaces between vacant
and predicted that new elements would be discovered which could
be fit in those spaces.
2. Correction of Atomic Masses
At the time of Mandeleev the atomic masses of some elements
were not correctly known. Mandeleev's classification of elements
help to correct the atomic masses of these elements.
3. Prediction About Properties
Mandeleev also made prediction about the properties of the unknown
elements. Many of these predictions were later found correct. He
was able to make these prediction because the elements falling in
the same group have similar properties.
4. Unication of Elements
Mandeleev's classification co-relates all the elements.
The discovery of periodic classification showed that all the elements
despite their apparent diversity are co-related with one another
and make one systematic whole. Thus, all the elements are unified
through a classification.
Periods
There are seven periods (horizontal rows) in the periodic table.
The first table period contains two elements that are hydrogen and
helium. The second and third periods have eight elements andeach
are called short periods. The fourth and fifth periods have eighteen
elements each and are called long term. The sixth period contains
thirty two elements and is called very long period. The seventh
period is incomplete. The properties change gradually within the
period or across the table from left to right.
Groups
The vertical columns in the periodic table are called groups or
families. There are thirty-two groups or vertical columns in the
modern periodic table. There are light groups, which consist of
five or six elements and are called main groups, represented by
'A' group, to distinguish them from remaining smaller groups by
Transition Elements. The elements of main groups are called Representative
Elements or Typical Elements.
The remaining groups that are the short groups of the periodic table
are known as transition group. The elements of these groups are
collectively called transition elements. These elements are further
classified into outer transition elements and inner transition elements.
The elements of outer transition elements (d-block) are usually
known as 'B' group. The transition elements of 'B' group consist
of eight groups and three periods, which are known as a Series.
The first series of outer transition elements started from Sc (Scandium)
to Zn (Zinc).
The inner transition elements (f-block) consist of two series of
elements having fourteen elements each. The first series of inner
transition elements is called Lanthanide series and the elements
are called Lanthanide's. The second series of inner transition elements
is called Actinide series and the elements are called Actinides.
The Lanthanide and Actinide are also known as Rear Earth Elements
and Heavy Rear Earth Elements respectively.
Blocks of Periodic Table
On the basis of the kind of orbital of elements occupied by the
last electron, the periodic table is classified into four blocks.
1. s - Block Elements
Those elements in which the last electron occupies
's' orbital are called s - block of the periodic table. The elements
of IA and IIA including hydrogen and helium are called s - Block
Elements.
2. p - Block Elements
Those elements in which the last electron occupies 'p'
orbital are called p - Block Elements of periodic table. The elements
of IIIA to VIIIA (six groups) are p - block elements.
3. d - Block Elements
Those elements in which last electron occupies 'd' orbital
are called d - Block Elements. The outer transition elements that
is B group (10 groups) belongs to d - block of Periodic Table.
4. f - Block Elements
Those elements in which last electron occupies 'f' orbital
are called f - Block Elements. The elements of inner transition
(14 groups) that is Lanthanide Series and Actinide Series belongs
to f - block elements. |